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李岱洲 教授

李岱洲 教授
Tai-Chou Lee
1996 國立台灣大學 化學工程學系 學士
2002 美國萊斯大學 化學工程學系 博士
分機: 34211
研究室: 工程一館 E302
實驗室: 材料與界面化學實驗室 E309
Email: taichoulee@ncu.edu.tw
王孝方教授照片

研究領域

表面科學，溼式化學法合成材料，能源應用。

研究說明 

Lee research group emphasizes the integration of materials synthesis, interfacial properties, and applications. Group members are expected to develop skills and knowledge of fundamental understanding of the problems, scientific approaches, and applications of final products. 

1. Surface modification (表面處理)
The surface modification technique employed in our laboratory focuses on the formation of self-assembled monolayers (SAM) on various substrates. This organic thin film derived from the adsorption of molecules on solid substrates has been extensively studied over the past two decades. These spontaneously adsorbed thin molecular films have thickness ranging from few Å to 2 nm. Due to the functional group tethered at the end of the molecule, the surface properties can be greatly changed. This unique property provides potential applications in many areas, such as biomaterials fabrication, lithographic patterning, and thin-film lubrication. In recent years, we have developed a standard procedure to generate high quality SAMs on oxide and silicon substrates. These modified substrates will be used for further inorganic thin film fabrications and colloidal particle self-assembly studies.

2. Material synthesis using wet chemistry process (濕式化學法合成材料)
In our laboratory, materials synthesis is generally divided into two directions: (1) particle/nanoparticle synthesis; (2) thin film deposition. Wet chemistry process is used for particle and thin film fabrication. Currently, we focus on the generation of metal sulfide compound semiconductor, including ZnS, AgInS2, AgIn5S8, and ZnS-AgInS2 solid solutions. For the particle system, final products depend strongly on the details of the solution chemistry. We have investigated the effects of chelating agent, pH value, and concentrations of the precursor solutions. The next step is to develop a robust protocol to precisely control the morphology, composition, and crystal structures of the particles. For the thin film system, these metal sulfides are deposited on the modified substrates. Self-assembled monolayers (SAMs) with various functional groups are tethered onto the substrate surface in order to manipulate the surface properties. As a result, different compositions and phases of the sulfide thin films can be easily fabricated.

3. Energy applications (能源應用)
Two types of energy applications are under investigation: (1) solar hydrogen production and (2) energy storage systems, typically various battery systems. For the solar hydrogen production, we study the solar-to-fuel conversion using photocatalytic and photoelectrochemical (PEC) system. The metal sulfide materials mentioned above, are used as the active materials for hydrogen production from water splitting. The fundamental materials properties, as well as the charge transfer inside the system are investigated. For the battery systems, we will explore the utilization of metal sulfide materials as the negative terminal.

論文著作

SELECTED PUBLICATIONS

  1. Cai, J.-W.; Wu, L.-M.; Lee, W.-H.; Chuang, C.-E.; Lee, T.-C. Optimized Nickel Phosphate Cocatalyst on Ge-Doped Hematite Photoanode for Selective Oxidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic Acid. ACS Sustainable Chem. Eng. 2025, 13, 5483-5492.

  2. Puspitasari, D. A.; Patra, J.; Hernandha, R. F. H.; Chiang, Y.-S.; Inoishi, A.; Chang, B. K.; Lee, T.-C.; Chang, J.-K. Enhanced Electrochemical Performance of Ca-Doped Na3v2(Po4)2f3/C Cathode Materials for Sodium-Ion Batteries. ACS Appl. Mater. Interfaces 2024, 16, 496-506.
  3. Lin, Y.-T.; Lee, C.-Y.; Wu, C.-Y.; Lin, J.-M.; Lee, T.-C.; Tung, S.-H.; Liu, C.-L. High Thermoelectric Performance of Spray-Coated Poly(3,4-Ethylenedioxythiophene):Poly(Styrenesulfonate) Films Enabled by Two-Step Post-Treatment Process. J. Power Sources 2023, 556, 232516.
  4. Rath, P. C.; Jheng, Y.-S.; Chen, C.-C.; Tsai, C.-L.; Su, Y.-S.; Yang, C.-C.; Eichel, R.-A.; Hsieh, C.-T.; Lee, T.-C.; Chang, J.-K. Tape-Cast Ce-Substituted Li7la3zr2o12 Electrolyte for Improving Electrochemical Performance of Solid-State Lithium Batteries. J. Mater. Chem. A 2022, 10, 22512-22522.
  5. Puspitasari, D. A.; Patra, J.; Hung, I. M.; Bresser, D.; Lee, T.-C.; Chang, J.-K. Optimizing the Mg Doping Concentration of Na3v2–Xmgx(Po4)2f3/C for Enhanced Sodiation/Desodiation Properties. ACS Sustainable Chem. Eng. 2021, 9, 6962-6971.
  6. Mishra, M.; Huang, Y.-C.; Wang, P.-H.; Liu, S.-P.; Lee, T. R.; Lee, T.-C. Tuning the Crystallinity and Coverage of Sio2–Znin2s4 Core–Shell Nanoparticles for Efficient Hydrogen Generation. ACS Appl. Mater. Interfaces 2021, 13, 4043-4050.
  7. Adhitama, E.; Rath, P. C.; Prayogi, A.; Patra, J.; Lee, T.-C.; Li, J.; Chang, J.-K. High-Voltage Lithium-Metal Battery with Three-Dimensional Mesoporous Carbon Anode Host and Ether/Carbonate Binary Electrolyte. Carbon 2021, 184, 752-763.
  8. Mishra, M.; Hsu, C.-W.; Rath, P. C.; Patra, J.; Lai, H.-Z.; Chang, T.-L.; Wang, C.-Y.; Wu, T.-Y.; Lee, T.-C.; Chang, J.-K. Ga-Doped Lithium Lanthanum Zirconium Oxide Electrolyte for Solid-State Li Batteries. Electrochim. Acta 2020, 353, 136536.
  9. Medhi, R.; Li, C.-H.; Lee, S. H.; Srinoi, P.; Marquez, M. D.; Robles-Hernandez, F.; Jacobson, A. J.; Lee, T.-C.; Lee, T. R. Antimony- and Zinc-Doped Tin Oxide Shells Coated on Gold Nanoparticles and Gold–Silver Nanoshells Having Tunable Extinctions for Sensing and Photonic Applications. ACS Appl. Nano Mater. 2020, 3, 8958-8971.
  10. Wu, C.-J.; Rath, P. C.; Patra, J.; Bresser, D.; Passerini, S.; Umesh, B.; Dong, Q.-F.; Lee, T.-C.; Chang, J.-K. Composition Modulation of Ionic Liquid Hybrid Electrolyte for 5 V Lithium-Ion Batteries. ACS Appl. Mater. Interfaces 2019, 11, 42049-42056.
  11. Rath, P. C.; Wu, C.-J.; Patra, J.; Li, J.; Lee, T.-C.; Yeh, T.-J.; Chang, J. K. Hybrid Electrolyte Enables Safe and Practical 5 V Lini0.5mn1.5o4 Batteries. J. Mater. Chem. A 2019, 7, 16516-16525.
  12. Wu, Y.-H.; Guo, W.-R.; Mishra, M.; Huang, Y.-C.; Chang, J.-K.; Lee, T.-C. Combinatorial Studies on Wet-Chemical Synthesized Ti-Doped Α-Fe2o3: How Does Ti4+ Improve Photoelectrochemical Activity? ACS Appl. Nano Mater. 2018, 1, 3145-3154.
  13. Khantamat, O.; Li, C.-H.; Liu, S.-P.; Liu, T.; Lee, H. J.; Zenasni, O.; Lee, T.-C.; Cai, C.; Lee, T. R. Broadening the Photoresponsive Activity of Anatase Tio2 Particles Via Decoration with Partial Gold Shells. J. Colloid Interface Sci. 2018, 513, 715-725.
  14. Li, H.-Y.; Tseng, C.-M.; Yang, C.-H.; Lee, T.-C.; Su, C.-Y.; Hsieh, C.-T.; Chang, J.-K. Eco-Efficient Synthesis of Highly Porous CoCO3 Anodes from Supercritical CO2 for Li+ and Na+ Storage. ChemSusChem 2017, 10, 2464-2472.
  15. Wu, K.; Wu, C.-J.; Tseng, C.-M.; Chang, J.-K.; Lee, T.-C. Structure-Mediated Electrochemical Performance of Sns2 Anode for Li-Ion Batteries. J. Taiwan Inst. Chem. Eng. 2016, 66, 292-300.
  16. Li, C.-H.; Li, M.-C.; Liu, S.-P.; Jamison, A. C.; Lee, D.; Lee, T. R.; Lee, T.-C. Plasmonically Enhanced Photocatalytic Hydrogen Production from Water: The Critical Role of Tunable Surface Plasmon Resonance from Gold-Silver Nanoshells. ACS Appl. Mater. Interfaces 2016, 8, 9152-9161.
  17. Hsu, C.-J.; Chou, C.-Y.; Yang, C.-H.; Lee, T.-C.; Chang, J.-K. Mos2/Graphene Cathodes for Reversibly Storing Mg2+ and Mg2+/Li+ in Rechargeable Magnesium-Anode Batteries. Chem. Commun. 2016, 52, 1701-1704.
  18. Wongittharom, N.; Wang, C.-H.; Wang, Y.-C.; Fey, G. T.-K.; Li, H.-Y.; Wu, T.-Y.; Lee, T.-C.; Chang, J.-K. Charge-Storage Performance of Li/LiFePO4 Cells with Additive-Incorporated Ionic Liquid Electrolytes at Various Temperatures. J. Power Sources 2014, 260, 268-275.
  19. Wongittharom, N.; Lee, T.-C.; Hung, I. M.; Lee, S.-W.; Wang, Y.-C.; Chang, J.-K. Ionic Liquid Electrolytes for High-Voltage Rechargeable Li/Lini0.5mn1.5o4 Cells. J. Mater. Chem. A 2014, 2, 3613-3620.
  20. Li, P.-C.; Hu, C.-C.; Lee, T.-C.; Chang, W.-S.; Wang, T. H. Synthesis and Characterization of Carbon Black/Manganese Oxide Air Cathodes for Zinc-Air Batteries. J. Power Sources 2014, 269, 88-97.
  21. Li, C.-H.; Jamison, A. C.; Rittikulsittichai, S.; Lee, T.-C.; Lee, T. R. In Situ Growth of Hollow Gold–Silver Nanoshells within Porous Silica Offers Tunable Plasmonic Extinctions and Enhanced Colloidal Stability. ACS Appl. Mater. Interfaces 2014, 6, 19943-19950.
  22. Lee, F.-Y.; Yang, K.-Y.; Wang, Y.-C.; Li, C.-H.; Lee, T. R.; Lee, T.-C. Electrochemical Properties of an AgInS2 Photoanode Prepared Using Ultrasonic-Assisted Chemical Bath Deposition. RSC Adv. 2014, 4, 35215-35223.
  23. Lin, P.-C.; Wang, P.-Y.; Li, Y.-Y.; Hua, C. C.; Lee, T.-C. Enhanced Photocatalytic Hydrogen Production over in-Rich (Ag-in-Zn)S Particles. Int. J. Hydrogen Energy 2013, 38, 8254-8262.
  24. Lai, C.-H.; Chiang, C.-Y.; Lin, P.-C.; Yang, K.-Y.; Hua, C. C.; Lee, T.-C. Surface-Engineered Growth of AgIn5S8 Crystals. ACS Appl. Mater. Interfaces 2013, 5, 3530-3540.
  25. Wu, C.-C.; Cho, H.-F.; Chang, W.-S.; Lee, T.-C. A Simple and Environmentally Friendly Method of Preparing Sulfide Photocatalyst. Chem. Eng. Sci. 2010, 65, 141-147.
  26. Chi, Y.-H.; Yen, P.-S.; Jeng, M.-S.; Ko, S.-T.; Lee, T.-C. Preparation of Thin Pd Membrane on Porous Stainless Steel Tubes Modified by a Two-Step Method. Int. J. Hydrogen Energy 2010, 35, 6303-6310.
  27. Chang, W.-S.; Wu, C.-C.; Jeng, M.-S.; Cheng, K.-W.; Huang, C.-M.; Lee, T.-C. Ternary Ag–in–S Polycrystalline Films Deposited Using Chemical Bath Deposition for Photoelectrochemical Applications. Mater. Chem. Phys. 2010, 120, 307-312.
  28. Lin, L.-H.; Wu, C.-C.; Lai, C.-H.; Lee, T.-C. Controlled Deposition of Silver Indium Sulfide Ternary Semiconductor Thin Films by Chemical Bath Deposition. Chem. Mater. 2008, 20, 4475-4483.
  29. Lin, L.-H.; Wu, C.-C.; Lee, T.-C. Growth of Crystalline Agin5s8 Thin Films on Glass Substrates from Aqueous Solutions. Cryst. Growth Des. 2007, 7, 2725-2732.
  30. Heller, D. A.; Garga, V.; Kelleher, K. J.; Lee, T.-C.; Mahbubani, S.; Sigworth, L. A.; Lee, T. R.; Rea, M. A. Patterned Networks of Mouse Hippocampal Neurons on Peptide-Coated Gold Surfaces. Biomaterials 2005, 26, 883-889.
  31. Lee, T.-C.; Hounihan, D. J.; Colorado, R., Jr.; Park, J.-S.; Lee, T. R. Stability of Aliphatic Dithiocarboxylic Acid Self-Assembled Monolayers on Gold. J. Phys. Chem. B 2004, 108, 2648-2653.
  32. Lee, T.-C.; Lee, J.-T.; Robert, M. A.; Wang, S.; Rabson, T. A. Surface Acoustic Wave Applications of Lithium Niobate Thin Films. Appl. Phys. Lett. 2003, 82, 191-193.